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Syllabus — Applied Chemistry for Emerging Electronics and Futuristic Devices Lab

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AAS152C / AAS252C · 1 credits · L-T-P 0-0-2

Course Objectives

  1. To study the electrical properties of conducting, semiconducting, and insulating materials
  2. To characterise electrochemical energy storage devices used in electronics
  3. To study properties of dielectric and magnetic materials relevant to electronic devices
  4. To synthesise and characterise nanomaterials and thin films for electronic applications
  5. To explore properties of organic and polymer-based electronic materials

List of Experiments

Exp.TheoryTitleDescription / Objective Unit
1Unit IElectrical Conductivity of Electrolyte SolutionsMeasure electrical conductivity of electrolyte solutions (NaCl, KCl, H2SO4) at varying concentrations using conductivity meter; determine limiting molar conductivity; relate to ionic conduction in electrolytes
2Unit IBand Gap of Semiconductor by Conductivity MethodMeasure electrical resistance of a semiconductor sample (Ge) at different temperatures; plot ln(R) vs 1/T; determine band gap energy; relate to semiconductor device material selection
3Unit IIEMF of Electrochemical Cell and Nernst EquationMeasure EMF of Daniell cell at varying ion concentrations; verify Nernst equation; relate to battery cell voltage and electrochemical energy device design
4Unit IICharge-Discharge Characteristics of SupercapacitorStudy charge and discharge curves of a supercapacitor; measure capacitance, energy density, and power density; compare with Li-ion battery; relate to energy storage in electronic devices
5Unit IIElectrodeposition of Thin Metal FilmElectrodeposit a thin copper or nickel film on a substrate; measure film thickness using gravimetric method; calculate current efficiency; relate to thin film technology in electronic device fabrication
6Unit IIIDielectric Constant of Insulating MaterialMeasure dielectric constant (permittivity) of a polymer film or ceramic material using LCR meter at varying frequencies; study frequency dependence; relate to capacitor dielectric selection
7Unit IIIMagnetic Properties – B-H Curve (Demonstration)Observe B-H hysteresis loop for soft and hard magnetic materials; determine retentivity, coercivity, and saturation magnetisation; relate to ferrite core materials in inductors and transformers
8Unit IVSynthesis of Silver Nanoparticles by Chemical ReductionSynthesise silver nanoparticles by reduction of AgNO3 with sodium borohydride; confirm formation by UV- Vis spectroscopy (plasmon peak ~420 nm); study size-dependent colour change
9Unit IVThin Film Deposition by Spin CoatingPrepare a thin polymer or sol-gel film on a glass substrate by spin coating; measure film thickness by Newton's rings method; relate to spin-coated films in OLEDs and photovoltaic devices
10Unit VElectrical Conductivity of ConductingSynthesise polyaniline by chemical oxidative polymerisation; measure its electrical conductivity using four-probe Polymer (Polyaniline) method at different doping levels; relate to organic electronics applications
11Unit VSolar Cell – I-V and P-V CharacteristicsPlot I-V and P-V curves of a solar cell; measure Voc, Isc, fill factor, and efficiency under different illumination levels; relate to photovoltaic chemistry and organic solar cells
12Unit IVUV-Vis Spectroscopy of Quantum Dots / Dye SolutionRecord UV-Vis absorption spectrum of a quantum dot solution or dye (methylene blue); study Beer-Lambert law; relate to optical properties of quantum dots in display and imaging applications

Equipment / Chemicals Required

  1. Conductivity meter and conductivity cell
  2. Temperature-controlled resistance measurement setup for semiconductor
  3. Electrochemical cell setup with voltmeter and salt bridge
  4. Supercapacitor charge-discharge test setup
  5. Electrodeposition setup (DC power supply, electrodes)
  6. LCR meter or impedance analyser
  7. B-H curve demonstrator / CRO
  8. UV-Vis spectrophotometer
  9. Spin coater and Newton's rings setup
  10. Four-probe conductivity meter
  11. Solar cell module with light source, rheostat, multimeters

Teaching-Learning Methodology

Each laboratory session begins with a 10-minute pre-lab discussion connecting the experiment to the corresponding theory unit. Students record aim, principle, apparatus, chemicals, procedure, observation table, calculations, result, and inference in the laboratory record book. Post-lab discussion relates experimental findings to real-world engineering applications in the respective stream. Students maintain a laboratory record book assessed for viva, record, and day-to-day performance.

Course Outcomes

COsCourse Outcome StatementKL
CO1Measure electrical conductivity of solutions and determine semiconductor band gapK3
CO2Characterise electrochemical cells, supercapacitors, and electrodeposited thin filmsK3
CO3Measure dielectric constant and observe magnetic hysteresis of electronic materialsK3
CO4Synthesise silver nanoparticles and characterise thin films by UV-Vis and optical methodsK3
CO5Measure conductivity of conducting polymers and characterise solar cell I-V behaviourK3

Evaluation Pattern

Sr.ComponentMarksWeightage
1.Day-to-day performance (Observation, Procedure, Conduct)2020%
2.Laboratory Record / File3030%
3.End Semester Practical Examination (Experiment + Viva Voce)5050%

Text Books

  1. Engineering Chemistry – Jain and Jain
  2. Electronic Properties of Materials – Rolf E. Hummel
  3. Nanomaterials: An Introduction to Synthesis, Properties and Applications – Vollath Safety and General Instructions
  4. Students must wear lab coat and safety goggles at all times in the chemistry laboratory
  5. Handle all acids, alkalis, and oxidising agents with extreme care; use fume hood for volatile chemicals
  6. Dispose of chemical waste in designated containers as per lab safety guidelines
  7. Do not pipette by mouth; use rubber bulb or mechanical pipette fillers
  8. Wash hands thoroughly after every experiment; report any spillage or accident immediately

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